But in case of the SOZ thrusters and their function for providing a short ullage burn to settle the propellants before the Blok D engine can start, the sanest time would be jettisoning them after the final ignition for descent as soon as the stack becomes suborbital on the moon.
It might be possible to jettison them already after the ignition for the final lunar orbit insertion. In that case, we assume that the thrusters on top of the LK can provide enough acceleration for a long enough time to permit engine start.